They eventually balanced after about 1.5hrs.
Next time will be less.
Time after that will be shorter again...
This might be an SFQ aka stupid f***ing question, but if charge terminates after about 15mins and around 1000mA CC, how do we know if charge has terminated on (15min) CV timeout or (1000mA) Termination Current.
You watch the graph on your PC and the current. If its balanced, all lines are at the top ad flat...
At this point, watch it. Anywhere from 5 mins, to 25 mins, or so it should end.
If its still going after half an hour, increase termination current.
If it ends as soon as the cells seemed balance (they only appear to be but are not yet) then reduce termination current.
Then take at least 10% capacity out (20+Ah) and try again. Its better to do this in use really.
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This is all to do try and do the following...
1. To MAKE SURE it is properly balanced to 99.5% (that means it must not only appear balanced (all lines on the graph at the top equal voltage) but should not need any significant current sucking out of the other cells by the balancer inthe charger to do this. And so that also means a low charge current by the charger to stay that way once balance is turned off/low. If we end the moment it looks balanced then the last cell to reach 3.600V or whatever you chose, isnt really full yet. The rest are, they were full some time ago - soaking at 3.600V! So IF we disconnect charger straight away that final cell will now drop faster than the rest as you watch on a cell log/monitor. So we have to decide how long post balance, is long enough. 15 mins approx after balance usually is.
2 Why noy set it so it stays "fully balanced" for longer? To ensure a full balance? Like 45 mins, 2 hours, etc? You could. But the cells hate being full. Hate being at any voltage above the natural free standing level. It causes degradation over time.
IF you want to do that, then set 3.550V as the charge voltage as then it doesent do much harm even after an hour or so post balance.
So that balanced on screen + 15 mins time length, depends on how well your set of cells balance, temperature, the balance current of the charger, etc.
In our case on the 230Ah cells that are very low impedance 15 mins seems OK. Not quite long enough... But after 5 or 6 charges they end up very very close. Just not on a single charge. Thats does the least harm, with the best balance and a complete charge.
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By doing this you have ENSURED a full balance,
while holding the battery at the elevated 3.600V
for the shortest time that you had to do. And thats the point!
You are aiming to avoid holding it at high voltage longer than needed, while getting a full balanced charge.
You can get a 100% charge at 3.650V, 3.600V, 3.550 equally. Every time you lower this, you still get a full charge as long as its 3.500V or above. But the balance and CV stage take ever longer to fully achieve.
The slower the battery balances (hello weedy BMS with 50mA Balance! like the common ones) the longer the battery has to stay at an elevated voltage. The shorter its lifespan.
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Charging a single cell as per spec sheet, at 3.650V and stopping as soon as it drops from that 0.5C (115A) charge to 11.5A is a different matter!
The REASON you stop at 11.5A (0.05C) is because the high charge voltage, means it IS fully charged, no need to torture it and wait longer, and the fact that you are not balancing anything.